Magnetic ground state of the one-dimensional ferromagnetic chain compounds<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:mi>M</mml:mi><mml:msub><mml:mrow><mml:mo>(</mml:mo><mml:mi>NCS</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mrow><mml:mo>(</mml:mo><mml:mi>thiourea</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mn>2</mml:mn></mml:msub></mml:mrow></mml:math>(<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:mi>M</…
نویسندگان
چکیده
The magnetic properties of the two isostructural molecule-based magnets, Ni(NCS)$_{2}$(thiourea)$_{2}$, $S$ = 1, [thiourea SC(NH$_2$)$_2$] and Co(NCS)$_{2}$(thiourea)$_{2}$, 3/2, are characterised using several techniques in order to rationalise their relationship with structural parameters ascertain changes caused by substitution spin. Zero-field heat capacity muon-spin relaxation measurements reveal low-temperature long-range ordering both compounds, addition Ising-like ($D < 0$) single-ion anisotropy ($D_{\rm{Co}} \sim$ -100 K, $D_{\rm{Ni}} -10 K). Crystal electronic structure, combined DC-field magnetometry, affirm highly quasi-one-dimensional behaviour, ferromagnetic intrachain exchange interactions $J_{\rm{Co}}\approx+4$ K $J_{\rm{Ni}}\sim+100$ weak antiferromagnetic interchain exchange, on $J'$ $\sim-0.1$ K. Electron charge spin-density mapping reveals through-space as a mechanism explain large discrepancy $J$-values despite, from perspective, similar pathways materials. Both species can be compared compounds $M$Cl$_2$(thiourea)$_4$, $M$ Ni(II) (DTN) Co(II) (DTC), where DTN is know harbour field-induced quantum critical points. Direct comparison DTC studied here shows that substituting halide Cl$^-$ ion, for NCS$^-$ results dramatic change properties.
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ژورنال
عنوان ژورنال: Physical Review Materials
سال: 2021
ISSN: ['2476-0455', '2475-9953']
DOI: https://doi.org/10.1103/physrevmaterials.5.034401